Highly Enantioselective Construction of Chiral Eight-Membered Cyclic Ethers through Tandem Cyclization of Ynones and Dicarbonyl Compounds.

DOI Number:

10.1021/acs.joc.4c02034
Link to literature

Reaction Category:

Cyclization | Cyclization | Further Cyclizations

MOP ID:

MOP_0000561

Educt:

dicarbonyl compounds, ynones

Product:

eight-membered cyclic ethers

Catalyst:

N-[(1S,2S)-2-[[[[(8α,9S)-6′-methoxycinchonan-9-yl]amino]thioxomethyl]amino]-1,2-diphenylethyl]-4-methyl-benzenesulfonamide

Cas No:

1295509-73-7

Associated Product from Buchler GmbH:

Quinine Base

Cas No:

130-95-0