Catalytic Enantioselective Total Syntheses of Bisorbicillinolide, Bisorbicillinol, and Bisorbibutenolide.

DOI Number:

10.1002/anie.200500480

Reaction Category:

MOP ID:

MOP_0000678

Educt:

1,1-dipropoxypropan-2-one, trimethylsilyl cyanide

Product:

(R)-2-methyl-3,3-dipropoxy-2-((trimethylsilyl)oxy)propanenitrile

Catalyst:

1,4-bis[[(8α,9R)-10,11-dihydro-6′-methoxy-cinchonan-9-yl]oxy]-9,10-Anthracenedione

Cas No:

176097-24-8

Cas No:

522-66-7