Stereodivergent Construction of Csp3− Csp3 Bonds Bearing Vicinal Stereocenters by Synergistic Palladium and Phase‐Transfer Catalysis.
DOI Number:
10.1002/anie.202215714
Reaction Category:
Educt:
tert-butyl 2-oxo-3-phenylindoline-1-carboxylate, (E)-buta-1,3-dien-1-ylbenzene
Product:
tert-butyl (R)-2-oxo-3-phenyl-3-((R,E)-4-phenylbut-3-en-2-yl)indoline-1-carboxylate
Catalyst:
di-μ-chlorobis(η3-2-propenyl)di-palladium, 4,4'-((3,3'-bis(3,5-bis(trifluoromethyl)phenyl)-5,5',6,6',7,7',8,8'-octahydro-[1,1'-binaphthalene]-2,2'-diyl)bis(oxy))didinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine, 1-[[3,5-bis(trifluoromethyl)phenyl]methyl]-9-hydroxy-6′-methoxy-cinchonanium bromide
Cas No:
945732-76-3
Associated Product from Buchler GmbH:
Quinidine Base
Cas No:
56-54-2