Organocatalytic Asymmetric Dearomatization of 3-Nitroindoles and 3-Nitrobenzothiophenes via Thiol-Triggered Diastereo- and Enantioselective Double Michael Addition Reaction.
DOI Number:
10.1021/acs.orglett.9b01688
Reaction Category:
RXNO ID:
RXNO_0000009
Educt:
ethyl (E)-4-mercaptobut-2-enoate, 3-nitrobenzothiophene
Product:
tetrahydrothiophenebenzothiophene
Catalyst:
(αR)-α-[[[[3,5-Bis(trifluoromethyl)phenyl]amino]thioxomethyl]amino]-N-[(8α,9S)-6′-methoxycinchonan-9-yl]benzenepropanamide
Cas No:
1509940-73-1
Associated Product from Buchler GmbH:
Quinine Base
Cas No:
130-95-0