Stereocontrolled desymmetrization of 2,5-cyclohexadienones via organocatalytic domino sulfa-1,6-/1,4-addition or sulfa-1,6-/1,4-/sulfa-1,4-addition reactions.
DOI Number:
10.1039/D4QO02097A
Reaction Category:
MOP ID:
MOP_0000561
Educt:
2,5-cyclohexadienones, p-toluenethiol
Product:
4-((4bR,8aS,9S,10S)-4b-methoxy-7-oxo-10-(p-tolylthio)-4b,7,8,8a,9,10-hexahydrophenanthren-9-yl)-2-oxo-2H-chromene-3-carbonitrile
Catalyst:
3-[[3,5-bis(trifluoromethyl)phenyl]amino]-4-[[(8α,9S)-6′-methoxycinchonan-9-yl]amino]-3-Cyclobutene-1,2-dione
Cas No:
1256245-84-7
Associated Product from Buchler GmbH:
3-[[3,5-bis(trifluoromethyl)phenyl]amino]-4-[[(8α,9S)-6′-methoxycinchonan-9-yl]amino]-3-Cyclobutene-1,2-dione
Cas No:
1256245-84-7