Organocatalytic Asymmetric Halogenation/Semipinacol Rearrangement: Highly Efficient Synthesis of Chiral α-Oxa-Quaternary β-Haloketones.
DOI Number:
10.1021/ja201794v
Reaction Category:
MOP ID:
MOP_0000551
Educt:
2-oxa allylic alcohols, N-bromoacetamide
Product:
β-bromo ketones
Catalyst:
(8α,9R)-(8′′α,9′′R)-9,9′′-[(2,5-Diphenyl-4,6-pyrimidinediyl)bis(oxy)]bis[10,11-dihydro-6′-methoxycinchonan]
Cas No:
149820-65-5
Associated Product from Buchler GmbH:
Dihydroquinine Base
Cas No:
522-66-7