Aza-Michael Addition, tert-butyl (naphthalen-2-ylmethoxy)carbamate, cyclic enones, N-substituted tert-butyl (naphthalen-2-ylmethoxy)carbamate, (8α,9S)-9-[[[[3,5-bis(trifluoromethyl)phenyl]amino]carbonyl]amino]-1-[[3,5-bis(trifluoromethyl)phenyl]methyl]-6′-methoxy-Cinchonanium bromide, Quinine Derivative

Asymmetric Phase-Transfer Catalytic aza-Michael Addition to Cyclic Enone: Highly Enantioselective and Diastereoselective Synthesis of Cyclic 1,3-Aminoalcohols.

DOI Number:

10.1021/acs.orglett.2c00192

Link to literature

Reaction Category:

Aza-Michael | Michael Addition

RXNO ID:

RXNO_0000009

Educt:

tert-butyl (naphthalen-2-ylmethoxy)carbamate, cyclic enones

Product:

N-substituted tert-butyl (naphthalen-2-ylmethoxy)carbamate

Catalyst:

(8α,9S)-9-[[[[3,5-bis(trifluoromethyl)phenyl]amino]carbonyl]amino]-1-[[3,5-bis(trifluoromethyl)phenyl]methyl]-6′-methoxy-Cinchonanium bromide

Cas No:

2762290-06-0

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Associated Product from Buchler GmbH:

Quinine Base

Cas No:

130-95-0