Asymmetric Phase-Transfer Catalytic aza-Michael Addition to Cyclic Enone: Highly Enantioselective and Diastereoselective Synthesis of Cyclic 1,3-Aminoalcohols.

DOI Number:

10.1021/acs.orglett.2c00192

Reaction Category:

Educt:

tert-butyl (naphthalen-2-ylmethoxy)carbamate, cyclic enones

Product:

N-substituted tert-butyl (naphthalen-2-ylmethoxy)carbamate

Catalyst:

(8α,9S)-9-[[[[3,5-bis(trifluoromethyl)phenyl]amino]carbonyl]amino]-1-[[3,5-bis(trifluoromethyl)phenyl]methyl]-6′-methoxy-Cinchonanium bromide

Cas No:

2762290-06-0

Cas No:

130-95-0