Enantioselective conjugate azidation of α,β-unsaturated ketones under bifunctional organocatalysis by direct activation of TMSN3.

DOI Number:

10.1002/adsc.201900831

Reaction Category:

RXNO ID:

RXNO_0000009

Educt:

alpha,beta-unsaturated ketones, azidotrimethylsilane

Product:

beta-azidoketones

Catalyst:

3-[[3,5-bis(trifluoromethyl)phenyl]amino]-4- [[(8α,9S)-6′-methoxycinchonan-9-yl]amino]- 3-Cyclobutene-1,2-dione

Cas No:

1256245-84-7

Cas No:

130-95-0