Enantioselective aza-Henry reaction using cinchona organocatalysts.

DOI Number:

10.1016/j.tet.2005.09.076
Link to literature

Reaction Category:

Aza-Henry | Henry | Mannich | Nitro-Mannich

RXNO ID:

RXNO_0000235

Educt:

tert-butyl (E)-(4-chlorobenzylidene)carbamate, nitromethane

Product:

tert-butyl (S)-(1-(4-chlorophenyl)-2-nitroethyl)carbamate

Catalyst:

N-[3,5-Bis(trifluoromethyl)phenyl]-N′- [(8α,9S)-6′-methoxycinchonan-9-yl]thiourea

Cas No:

852913-16-7

Associated Product from Buchler GmbH:

Quinine Base

Cas No:

130-95-0