Highly enantioselective aza-henry reaction of ketimines catalyzed by a chiral bifunctional thiourea-tertiary amine derived from quinine.

DOI Number:

10.1016/j.tetlet.2018.10.039

Reaction Category:

RXNO ID:

RXNO_0000235

Educt:

ketimines, nitromethane

Product:

substituted 2-((4-methylphenyl)sulfonamido)-3-nitropropanoate

Catalyst:

N-[3,5-Bis(trifluoromethyl)phenyl]-N′-[(8α,9S)-6′-methoxycinchonan-9-yl]thiourea

Cas No:

852913-16-7

Cas No:

130-95-0