Synthesis of Atropisomeric Two‐Axis Systems by the Catalyst‐Controlled syn‐and anti‐Selective Arene‐Forming Aldol Condensation.
DOI Number:
10.1002/anie.202202548
Reaction Category:
MOP ID:
MOP_0000561
Educt:
1-(2-(1-naphthoyl)phenyl)-3-(o-tolyl)propan-2-one, acetic anhydride
Product:
(1S,2R)-2-(o-tolyl)-[1,1'-binaphthalen]-3-yl acetate
Catalyst:
(9S)-9-hydroxy-1-(phenylmethyl)- cinchonanium bromide
Cas No:
85653-34-5
Associated Product from Buchler GmbH:
Cinchonine Base
Cas No:
118-10-5