Synthesis of Atropisomeric Two‐Axis Systems by the Catalyst‐Controlled syn‐and anti‐Selective Arene‐Forming Aldol Condensation.

DOI Number:

10.1002/anie.202202548

Reaction Category:

MOP ID:

MOP_0000561

Educt:

1-(2-(1-naphthoyl)phenyl)-3-(o-tolyl)propan-2-one, acetic anhydride

Product:

(1S,2R)-2-(o-tolyl)-[1,1'-binaphthalen]-3-yl acetate

Catalyst:

(9S)-9-hydroxy-1-(phenylmethyl)- cinchonanium bromide

Cas No:

85653-34-5

Cas No:

118-10-5