Cocatalyst-Dependent Divergent Amination of Alkylgold Intermediates with Azodicarboxylates.

DOI Number:

10.1021/acscatal.5c00495
Link to literature

Reaction Category:

Amination | Cyclization | Cyclization | Further Cyclizations

MOP ID:

MOP_0000561

Educt:

N-propynylacetamides, azodicarboxylates

Product:

gold-catalyst, 3-[[(8α,9S)-6′-methoxycinchonan-9-yl]amino]-4-(phenylamino)-3-cyclobutene-1,2-dione

Catalyst:

3-[[(8α,9S)-6′-methoxycinchonan-9-yl]amino]-4-(phenylamino)-3-cyclobutene-1,2-dione

Cas No:

1528740-10-4

Associated Product from Buchler GmbH:

Quinine Base

Cas No:

130-95-0