Recyclable BINOL–quinine–squaramide as a highly efficient organocatalyst for α-amination of 1,3-dicarbonyl compounds and α-cyanoacetates.

DOI Number:

10.1039/C4RA13789B

Reaction Category:

Educt:

Diethyl azodicarboxylate, Methyl 2-oxocyclopentanecarboxylate

Product:

1,2-Diethyl 1-[(1S)-1-(methoxycarbonyl)-2-oxocyclopentyl]-1,2-hydrazinedicarboxylate

Catalyst:

3-[[[(1S)-2,2′-dihydroxy[1,1′-binaphthalen]-3-yl]methyl]amino]-4-[[(9S)-6′-methoxycinchonan-9-yl]amino]-3-cyclobutene-1,2-dione

Cas No:

1486483-03-7

Cas No:

1486483-03-7