Enantioconvergent Cu-catalyzed radical C–N coupling of racemic secondary alkyl halides to access α-chiral primary amines.

DOI Number:

10.1021/jacs.1c07726

Reaction Category:

Educt:

(1-bromoethyl)benzene, S,S-diphenylsulfoximine

Product:

(αR)-α-Methyl-N-(oxidodiphenyl-λ4-sulfanylidene)benzenemethanamine

Catalyst:

(2-thiophenecarboxylato-κO2,κS1)-copper, 2-[bis[3,3′′,5,5′′-tetrakis(1,1-dimethylethyl)[1,1′:3′,1′′-terphenyl]-5′-yl]phosphino]-N-[(8α,9R)-6′-methoxycinchonan-9-yl]-benzamide

Cas No:

2708150-47-2

Cas No:

56-54-2