Organocatalytic enantioselective formal C(sp 2 )–H alkylation.

DOI Number:

10.1021/ja5117556
Link to literature

Reaction Category:

Desymmetrization

Educt:

2,2-disubstituted cyclopentene-1,3-diones, nitroalkanes

Product:

4-alkyl-2,2-disubstitutedcyclopentene-1,3-diones

Catalyst:

N-[3,5-Bis(trifluoromethyl)phenyl]-N′-[(8α,9S)-10,11-dihydro-6′-methoxycinchonan-9-yl]-Urea

Cas No:

871334-33-7

Associated Product from Buchler GmbH:

Dihydroquinine Base

Cas No:

522-66-7