Enantioselective Synthesis of cis- and trans-Cycloheptyl β‑Fluoro Amines by Sequential aza-Henry Addition/Ring-Closing Metathesis.
DOI Number:
10.1021/acs.orglett.2c04285
Reaction Category:
MOP ID:
MOP_0000369
Educt:
tert-butyl (1-tosylpent-4-en-1-yl)carbamate, 4-fluoro-4-nitrobut-1-ene
Product:
tert-butyl ((4S,5R)-4-fluoro-4-nitronona-1,8-dien-5-yl)carbamate
Catalyst:
(8α,9R)-9-hydroxy-6′-methoxy-1-(phenylmethyl)-Cinchonanium chloride
Cas No:
67174-25-8
Associated Product from Buchler GmbH:
N-Benzylquininium Chloride
Cas No:
67174-25-8