Mechanism and Origin of Remote Stereocontrol in the Organocatalytic Enantioselective Formal C(sp2)–H Alkylation Using Nitroalkanes as Alkylating Agents.
DOI Number:
10.1021/jacs.2c02941
Reaction Category:
MOP ID:
MOP_0000369
Educt:
2-benzyl-2-methylcyclopent-4-ene-1,3-dione, nitromethane
Product:
(R)-2-benzyl-2,4-dimethylcyclopent-4-ene-1,3-dione
Catalyst:
N-[3,5-Bis(trifluoromethyl)phenyl]-N′-[(8α,9S)- 10,11-dihydro-6′-methoxycinchonan-9-yl]-Urea
Cas No:
871334-33-7
Associated Product from Buchler GmbH:
Dihydroquinine Base
Cas No:
522-66-7