Organocatalytic Asymmetric Aldol Reaction of Ketones with β,γ‐Unsaturated α‐Keto Esters: An Efficient Access to Chiral Tertiary Alcohol Skeletons.

DOI Number:

10.1002/adsc.201000982
Link to literature

Reaction Category:

Aldol | Aldol

RXNO ID:

RXNO_0000016

Educt:

β,γ‐unsaturated α‐keto esters, cyclohexanone

Product:

methyl (R,E)-2-hydroxy-2-((S)-2-oxocyclohexyl)-4-phenylbut-3-enoate

Catalyst:

(9R)-Cinchonan-9-amine

Cas No:

168960-96-1

Associated Product from Buchler GmbH:

Cinchonine Base

Cas No:

118-10-5