Stereodivergence in amine-catalyzed regioselective [4+2] cycloadditions of β-substituted cyclic enones and polyconjugated malononitriles.
DOI Number:
10.1021/ja3106219
Reaction Category:
MOP ID:
MOP_0000565
Educt:
beta-substituted cyclic enones, polyconjugated malononitriles
Product:
substituted (1R,3S,4R)-1-methyl-5-oxo-3-((E)-prop-1-en-1-yl)bicyclo[2.2.2]octane-2,2-dicarbonitrile
Catalyst:
(9R)-6′-methoxy-cinchonan-9-amine
Cas No:
287979-82-2
Associated Product from Buchler GmbH:
Quinidine Base
Cas No:
56-54-2