Catalytic asymmetric [4+2] additions with aliphatic nitroalkenes.
DOI Number:
10.1039/c1sc00326g
Reaction Category:
MOP ID:
MOP_0000565
Educt:
4-substituted 3-hydroxy-2H-pyran-2-one, aliphatic nitroalkenes
Product:
(5,7R)-substituted (1R,4S,8R)-4-hydroxy-8-nitro-2-oxabicyclo[2.2.2]oct-5-en-3-one
Catalyst:
(9S)-10,11-dihydro-9-[[tris(1-methylethyl)silyl]oxy]-cinchonan-6′-ol
Cas No:
1352335-41-1
Associated Product from Buchler GmbH:
Dihydrocupreidine Base
Cas No:
73522-75-5