Metal-Free Diastereo- and Enantioselective Dearomative Formal [3 + 2] Cycloaddition of 2-Nitrobenzofurans and Isocyanoacetate Esters.
DOI Number:
10.1021/acs.orglett.2c00427
Reaction Category:
MOP ID:
MOP_0000715
Educt:
2-nitrobenzofuran, methyl 2-cyano-2-phenylacetate
Product:
methyl (1R,3aR,8bR)-3a-nitro-1-phenyl-3a,8b-dihydro-1H-benzofuro[2,3-c]pyrrole-1-carboxylate
Catalyst:
(8α,9R)-9-(1-Naphthalenylmethoxy)cinchonan-6′-ol
Cas No:
1391097-86-1
Associated Product from Buchler GmbH:
Cupreine Base
Cas No:
524-63-0