Organocatalytic asymmetric formal [3+2] cycloaddition with in situ-generated N-carbamoyl nitrones.
DOI Number:
10.1021/ja902458m
Reaction Category:
MOP ID:
MOP_0000715
Educt:
dimethyl pent-2-enedioate, tert-butyl hydroxy(3-phenyl-1-(phenylsulfonyl)propyl)carbamate
Product:
2-(tert-butyl) 4-methyl (3R,4R,5S)-5-(2-methoxy-2-oxoethyl)-3-phenethylisoxazolidine-2,4-dicarboxylate
Catalyst:
(8α,9R)-9-(2,2-dimethyl-1-oxopropoxy)-6′-methoxy-1-[(2-nitrophenyl)methyl]-cinchonanium chloride
Cas No:
1173451-63-2
Associated Product from Buchler GmbH:
Cinchonidine Base
Cas No:
485-71-2