Catalytic enantioselective alkylative dearomatization−annulation: total synthesis and absolute configuration assignment of hyperibone K.
DOI Number:
10.1021/ja1057828
Reaction Category:
MOP ID:
MOP_0000561
Educt:
substituted phenyl(2,4,6-trihydroxyphenyl)methanone, 3-formyl-2-methylbut-3-en-2-yl 2-oxoheptanoate
Product:
hyperibone K
Catalyst:
(3β,8α,9R)-(3′′β,8′′α,9′′R)-1,1′′-[1,3-phenylenebis(methylene)]bis[3-(2-methyl-1-propen-1-yl)-9-(phenylmethoxy)-10,11-dinorcinchonanium Bromide
Cas No:
1246968-58-0
Associated Product from Buchler GmbH:
Cinchonidine Base
Cas No:
485-71-2