Enantioselective α-Trifluoromethylthiolation of Carbonyl Compounds with AgSCF3 and Trichloroisocyanuric Acid.
DOI Number:
10.1021/acs.joc.4c00661
Reaction Category:
MOP ID:
MOP_0000553
Educt:
methyl 7-bromo-1-oxo-1,2,3,4-tetrahydronaphthalene-2-carboxylate, Trichloroisocyanuric Acid, Trifluoromethanethiol silver salt
Product:
methyl (S)-7-bromo-1-oxo-2-((trifluoromethyl)thio)-1,2,3,4-tetrahydronaphthalene-2-carboxylate
Catalyst:
3-[(8α,9S)-Cinchonan-9-ylamino]-4-[[4-(trifluoromethyl)phenyl]amino]-3-cyclobutene-1,2-dione
Cas No:
1256245-87-0
Associated Product from Buchler GmbH:
Cinchonidine Base
Cas No:
485-71-2