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Conia-ene reaction, methyl 2-benzoylhept-6-ynoate, methyl (R)-1-benzoyl-2-methylenecyclopentane-1-carboxylate, N-[3,5-Bis(trifluoromethyl)phenyl]-N′-(8α,9S)-cinchonan-9-ylurea, Cinchonidine Derivative

Conia-ene reaction, Further reactions

Spirocyclization, isatin, malononitrile, ethyl acetoacetate, ethyl (S)-2′-amino-3′-cyano-6′-methyl-2-oxospiro[indoline-3,4′-pyran]-5′-carboxylate, N-[3,5-Bis(trifluoromethyl)phenyl]-N′-(8α,9S)-cinchonan-9-ylthiourea, Cinchonidine Derivative

Spirocyclization

Decarboxylative Protonation, 2-acetamido-2-benzyl-3-ethoxy-3-oxopropanoic acid, ethyl acetyl-D-phenylalaninate, N-(8α,9S)-Cinchonan-9-ylbenzenecarbothioamide, Cinchonidine Derivative

Decarboxylative Protonation, Protonation

Hydrosilylation, (S,E)-1-(3-(benzyloxy)phenyl)-N-(1-phenylethyl)ethan-1-imine, trichlorosilane, (S)-1-(3-(benzyloxy)phenyl)-N-((S)-1-phenylethyl)ethan-1-amine, (8α,9S)-1-(phenylmethyl)-9-[(2-pyridinylcarbonyl)amino]-Cinchonanium bromide, Cinchonidine Derivative

Further reactions, Hydrogenation, Hydrogenation of imines, Hydrosilylation, Reduction

Isomerization of imines, trifluoromethyl imines, alkyl trifluoromethylated amines, (8α,9R)-2′-Chloro-10,11-dihydro-6′-methoxycinchonan-9-ol, Dihydroquinine Derivative

Isomerization

Isomerization of imines, (E)-2,2,2-trifluoro-N-(4-nitrobenzyl)-1-phenylethan-1-imines, (R,E)-1-(4-nitrophenyl)-N-(2,2,2-trifluoro-1-phenylethyl)methanimines, (8α,9R)-2′-Chloro-10,11-dihydro-6′-methoxycinchonan-9-ol, Dihydroquinine Derivative

Isomerization

Alkylation, gramine, tert-Butyl N-(diphenylmethylene)glycinate, N-(Diphenylmethylene)-L-tryptophan 1,1-dimethylethyl ester, O-Allyl-1-(anthracen-9-ylmethyl)-cinchonidinium Bromide, Cinchonidine Derivative

Alkylation, Alkylation

Hydrosilylation, (E)-N,1-diphenylpropan-1-imine, trichlorosilane, (R)-N-(1-phenylpropyl)aniline, 2-[[(8α,9S)-cinchonan-9-ylamino]carbonyl]-1-methyl-Pyridinium tetrafluoroborate, Cinchonidine Derivative

Hydrogenation, Hydrogenation of imines, Hydrosilylation

Alkylation, methyl 1-oxo-2,3-dihydro-1H-indene-2-carboxylate, ethyl 2,2-difluoro-2-iodoacetate, methyl (R)-2-(2-ethoxy-1,1-difluoro-2-oxoethyl)-1-oxo-2,3-dihydro-1H-indene-2-carboxylate, 1-[2-([1,1′-biphenyl]-2-ylamino)-2-oxoethyl]- 9-hydroxy-(8α,9R)-Cinchonanium bromide, Cinchonidine Derivative

Alkylation, Alkylation

Alkylation, tert-butyl (1-benzyl-2-oxoindolin-3-yl)(2-chloroethyl)carbamate, tert-butyl (S)-1′-benzyl-2′-oxospiro[azetidine-2,3′-indoline]-1-carboxylate, (1S,2S,4S,5R)-2-((R)-hydroxy(quinolin-4-yl)methyl)-1-(4-(pentafluoro-l6-sulfaneyl)benzyl)-5-vinylquinuclidin-1-ium bromide, Cinchonidine Derivative

Alkylation, Alkylation, Spirocyclization

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