Remote Control of Axial Chirality: Aminocatalytic Desymmetrization of N-Arylmaleimides via Vinylogous Michael Addition.

DOI Number:

10.1021/ja505610k

Reaction Category:

Educt:

3-ethylcyclohex-2-en-1-one, N-(2-tert-Butylphenyl)maleimide

Product:

(R)-1-(2-(tert-butyl)phenyl)-3-((R)-1-(3-oxocyclohex-1-en-1-yl)ethyl)pyrrolidine-2,5-dione

Catalyst:

N-Boc-L-phenylglycine, (8α,9S)-6′-Methoxycinchonan-9-amine

Cas No:

168960-95-0

Cas No:

130-95-0