Enantioselective Addition of Thiols to Acyclic Ketiminoesters Using Cinchona Alkaloid Amide/Zinc (II) Catalysts.
DOI Number:
10.1002/adsc.202400674
Reaction Category:
Educt:
N-protected ethyl 2-imino-4-phenylbut-3-ynoate, 3-((trimethylsilyl)oxy)propane-1-thiol
Product:
N-protected ethyl (R)-2-amino-2-((3-hydroxypropyl)thio)-4-phenylbut-3-ynoate
Catalyst:
diethylzinc, N-[(8α,9S)-10,11-dihydrocinchonan-9-yl]-2-pyridinecarboxamide
Cas No:
Associated Product from Buchler GmbH:
Dihydrocinchonidine Base
Cas No:
485-64-3