Copper-Catalyzed Chemo-and Enantioselective Radical 1, 2-Carbosulfenylation of Diverse Alkenes with Broad Radical and Sulfur Compatibility.

DOI Number:

10.1021/jacs.6c14452
Link to literature

Reaction Category:

Further reactions | Thiolation

Educt:

1-(9H-carbazol-9-yl)prop-2-en-1-one, potassium benzothioate, ethyl 2-bromo-2-methylpropanoate

Product:

ethyl 4-(benzoylthio)-5-(9H-carbazol-9-yl)-2,2-dimethyl-5-oxopentanoate

Catalyst:

copper catalyst, (E)-2-((2,6-diisopropylphenyl)imino)-2-(2-isopropylphenyl)-N-((S)-(6-methoxyquinolin-4-yl)((1S,2S,4S,5R)-5-vinylquinuclidin-2-yl)methyl)acetamide

Cas No:

Associated Product from Buchler GmbH:

Quinine Base

Cas No:

130-95-0