Catalytic Asymmetric Conjugate Addition of Mercaptans to β‐Substituted‐β‐Trifluoromethyl Oxazolidinone Enoates: Access to Chiral Trifluoromethylated Tertiary Thioethers and Thiols.
DOI Number:
10.1002/adsc.201301027
Reaction Category:
RXNO ID:
RXNO_0000009
Educt:
β‐substituted‐β‐trifluoromethyl oxazolidinone enoates, mercaptans
Product:
substituted 3-(4,4,4-trifluoro-3-mercaptobutanoyl)oxazolidin-2-one
Catalyst:
3-[[3,5-bis(trifluoromethyl)phenyl]amino]-4-[[(8α,9S)-6′-methoxycinchonan-9-yl]amino]-3-Cyclobutene-1,2-dione
Cas No:
1256245-84-7
Associated Product from Buchler GmbH:
Quinine Base
Cas No:
130-95-0