Catalytic Asymmetric Conjugate Addition of Mercaptans to β‐Substituted‐β‐Trifluoromethyl Oxazolidinone Enoates: Access to Chiral Trifluoromethylated Tertiary Thioethers and Thiols.

DOI Number:

10.1002/adsc.201301027

Reaction Category:

Educt:

β‐substituted‐β‐trifluoromethyl oxazolidinone enoates, mercaptans

Product:

substituted 3-(4,4,4-trifluoro-3-mercaptobutanoyl)oxazolidin-2-one

Catalyst:

3-[[3,5-bis(trifluoromethyl)phenyl]amino]-4-[[(8α,9S)-6′-methoxycinchonan-9-yl]amino]-3-Cyclobutene-1,2-dione

Cas No:

1256245-84-7

Cas No:

130-95-0