Cinchona alkaloids-derived chiral ligands for Mn-catalyzed ATH of ketones: Improvement of enantioselectivity through π-π stacking-induced hydrogen bond.
DOI Number:
10.1016/j.jcat.2024.115758
Reaction Category:
MOP ID:
MOP_0000589
Educt:
1-(4-ethylphenyl)ethan-1-one
Product:
(S)-1-(4-ethylphenyl)ethan-1-ol
Catalyst:
manganese catalyst, (R)-N-(furan-2-ylmethyl)-1-(quinolin-4-yl)-1-((1S,2R,4S,5R)-5-vinylquinuclidin-2-yl)methanamine
Cas No:
Associated Product from Buchler GmbH:
Cinchonine Base
Cas No:
118-10-5