Monocationic Cinchoninium Catalyzed Asymmetric Oxohydroxylation of Enoates.

DOI Number:

10.1021/acscatal.1c04849

Reaction Category:

Educt:

alpha-alkyl enoates, potassium permanganate

Product:

alpha-hydroxy-beta-ketoesters

Catalyst:

(1S,2R,4S,5R)-2-((S)-((2-bromo-3,5-di-tert-butylbenzyl)oxy)(quinolin-4-yl)methyl)-1-(3,5-difluorobenzyl)-5-vinylquinuclidin-1-ium

Cas No:

2734067-65-1

Cas No:

118-10-5