Diastereodivergent Catalysis Using Modularly Designed Organocatalysts: Synthesis of both cis‐and trans‐Fused Pyrano [2,3‐b] pyrans.

DOI Number:

10.1002/anie.201510134

Reaction Category:

RXNO ID:

RXNO_0000006

Educt:

(E)-7-oxo-7-phenylhept-5-enal, methyl (E)-2-oxo-4-phenylbut-3-enoate

Product:

pyrano [2,3‐b] pyrans

Catalyst:

N-[3,5-Bis(trifluoromethyl)phenyl]-N′-[(9R)-6′-methoxycinchonan-9-yl]thiourea

Cas No:

852913-25-8

Associated Product from Buchler GmbH:

N-[3,5-Bis(trifluoromethyl)phenyl]-N′-[(9R)-6′-methoxycinchonan-9-yl]thiourea

Cas No:

852913-25-8