Enyne diketones as substrate in asymmetric Nazarov cyclization for construction of chiral allene cyclopentenones.
DOI Number:
10.1038/s41467-022-30846-y
Reaction Category:
Educt:
methyl 2-diazo-2-phenylacetate, (E)-4-methyl-1-phenylhex-4-en-1-yn-3-ol
Product:
(S)-5-hydroxy-2,3-dimethyl-5-phenyl-4-((R)-2-phenylvinylidene)cyclopent-2-en-1-one
Catalyst:
N,N′-bis[(8α,9S)-6′-methoxycinchonan-9-yl]-thiourea
Cas No:
1263049-13-3
Associated Product from Buchler GmbH:
Quinine Base
Cas No:
130-95-0