Total synthesis of (−)-nakadomarin A.

DOI Number:

10.1021/ja908399s

Reaction Category:

RXNO ID:

RXNO_0000009

Educt:

methyl (10aR,Z)-3-oxo-1,2,3,5,6,7,8,10a-octahydropyrrolo[1,2-a]azocine-2-carboxylate, 2-allyl-4-(2-nitroethyl)furan

Product:

methyl (2S,10aR,Z)-2-((S)-1-(5-allylfuran-3-yl)-2-nitroethyl)-3-oxo-1,2,3,5,6,7,8,10a-octahydropyrrolo[1,2-a]azocine-2-carboxylate

Catalyst:

N-[3,5-bis(trifluoromethyl)phenyl]-N′-(9R)-cinchonan-9-yl-urea

Cas No:

945985-98-8

Cas No:

118-10-5