Molecular Assembly of an Achiral Phosphine and a Chiral Primary Amine: A Highly Efficient Supramolecular Catalyst for the Enantioselective Michael Reaction of Aldehydes with Maleimides.

DOI Number:

10.1002/asia.201300141

Reaction Category:

RXNO ID:

RXNO_0000009

Educt:

maleimides, aldehydes

Product:

2-(1-substituted-2,5-dioxopyrrolidin-3-yl)-2-substituted-acetaldehyde

Catalyst:

(9R)-Cinchonan-9-amine, triphenylphosphine

Cas No:

168960-96-1

Cas No:

118-10-5