Molecular Assembly of an Achiral Phosphine and a Chiral Primary Amine: A Highly Efficient Supramolecular Catalyst for the Enantioselective Michael Reaction of Aldehydes with Maleimides.
DOI Number:
10.1002/asia.201300141
Reaction Category:
RXNO ID:
RXNO_0000009
Educt:
maleimides, aldehydes
Product:
2-(1-substituted-2,5-dioxopyrrolidin-3-yl)-2-substituted-acetaldehyde
Catalyst:
(9R)-Cinchonan-9-amine, triphenylphosphine
Cas No:
168960-96-1
Associated Product from Buchler GmbH:
Cinchonine Base
Cas No:
118-10-5