Catalytic asymmetric conjugate addition of α-substituted nitro acetates to nitro olefins: enantioselective synthesis of highly substituted γ-lactams.

DOI Number:

10.1002/ejoc.201201444

Reaction Category:

RXNO ID:

RXNO_0000009

Educt:

ethyl 2-nitropropanoate, nitro olefins

Product:

ethyl (2R)-3-substituted-2-methyl-2,4-dinitrobutanoates

Catalyst:

(8α,9R)-(8′′α,9′′R)-9,9′′-[1,4-Phthalazinediylbis (oxy)]bis[10,11-dihydrocinchonan-6′-ol

Cas No:

1256161-56-4

Cas No:

5962-19-6