Highly diastereodivergent synthesis of tetrasubstituted cyclohexanes catalyzed by modularly designed organocatalysts.
DOI Number:
10.1002/anie.201404072
Reaction Category:
MOP ID:
MOP_0000561
Educt:
(E)-7-oxo-7-phenylhept-5-enal, (E)-(2-nitrovinyl)benzene
Product:
(1R,2S,3R,4R)-3-nitro-4-(2-oxo-2-phenylethyl)-2-phenylcyclohexane-1-carbaldehyde
Catalyst:
L-proline, N-[3,5-Bis(trifluoromethyl)phenyl]-N′-[(9R)-6′-methoxycinchonan-9-yl]thiourea
Cas No:
852913-25-8
Associated Product from Buchler GmbH:
Quinidine Base
Cas No:
56-54-2