Enantioselective Organocatalytic Michael/Aldol Sequence: Anticancer Natural Product (+)‐trans‐Dihydrolycoricidine.

DOI Number:

10.1002/ange.201403065

Reaction Category:

MOP ID:

MOP_0000561

Educt:

(E)-3-(benzo[d][1,3]dioxol-5-yl)acrylaldehyde, 1-azidopropan-2-one

Product:

(2R,3R,5S)-2-azido-3-(benzo[d][1,3]dioxol-5-yl)-5-hydroxycyclohexan-1-one

Catalyst:

(R)-2-(diphenyl((trimethylsilyl)oxy)methyl)pyrrolidine, Quinidine Base

Cas No:

56-54-2

Cas No:

56-54-2