Organocatalytic Enantioselective Michael-Addition of Malonic Acid Half-Thioesters to β-Nitroolefins: From Mimicry of Polyketide Synthases to Scalable Synthesis of g-Amino Acids.

DOI Number:

10.1002/adsc.201100458

Reaction Category:

Educt:

(E)-(2-nitrovinyl)benzene, 3-((4-methoxyphenyl)thio)-3-oxopropanoic acid

Product:

S-(4-methoxyphenyl) (S)-4-nitro-3-phenylbutanethioate

Catalyst:

3-[[3,5-bis(trifluoromethyl)phenyl]amino]-4-[[(8α,9S)-6′-methoxycinchonan-9-yl]amino]-3-Cyclobutene-1,2-dione

Cas No:

1256245-84-7

Cas No:

130-95-0