Enantioselective synthesis of α-stereogenic γ-keto esters via formal umpolung.
DOI Number:
10.1021/ol301112m
Reaction Category:
RXNO ID:
RXNO_0000009
Educt:
(E)-1-(4-chlorophenyl)-3-phenylprop-2-en-1-one, ((nitromethyl)sulfonyl)benzene
Product:
(3R)-1-(4-chlorophenyl)-4-nitro-3-phenyl-4-(phenylsulfonyl)butan-1-one
Catalyst:
(9R)-6′-methoxy-cinchonan-9-amine
Cas No:
287979-82-2
Associated Product from Buchler GmbH:
Quinidine Base
Cas No:
56-54-2