Effect of high pressure on the organocatalytic asymmetric Michael reaction: Highly enantioselective synthesis of γ-nitroketones with quaternary stereogenic centers.
DOI Number:
10.1021/ol201275h
Reaction Category:
RXNO ID:
RXNO_0000009
Educt:
3-methylcyclohept-2-en-1-one, nitromethane
Product:
(R)-3-methyl-3-(nitromethyl)cycloheptan-1-one
Catalyst:
(9R)-Cinchonan-9-amine
Cas No:
168960-96-1
Associated Product from Buchler GmbH:
Cinchonine Base
Cas No:
118-10-5