Enantioselective Synthesis of Both Enantiomers of Methyl Dihydrojasmonate Using Solid−Liquid Asymmetric Phase-Transfer Catalysis.

DOI Number:

10.1021/ol006207e

Reaction Category:

RXNO ID:

RXNO_0000009

Educt:

2-pentylcyclopent-2-en-1-one, dimethyl malonate

Product:

dimethyl 2-((1R,2S)-3-oxo-2-pentylcyclopentyl)malonate

Catalyst:

(8α,9R)-1-(9-anthracenylmethyl)-9-hydroxy-6′- methoxy-cinchonanium chloride

Cas No:

199588-84-6

Associated Product from Buchler GmbH:

N-(9-Anthracenylmethyl)quininium Chloride

Cas No:

199588-84-6