Controlling the α/γ‐Reactivity of Vinylogous Ketone Enolates in Organocatalytic Enantioselective Michael Reactions.

DOI Number:

10.1002/anie.201703764

Reaction Category:

RXNO ID:

RXNO_0000009

Educt:

1-substituted hex-5-en-1-yn-3-one, nitroalkenes

Product:

substituted 4-(2-nitroethyl)hex-4-en-1-yn-3-one

Catalyst:

3-[[3,5-bis(trifluoromethyl)phenyl]amino]-4-[[(8α,9S)-6′-methoxycinchonan-9-yl]amino]-3-Cyclobutene-1,2-dione

Cas No:

1256245-84-7

Associated Product from Buchler GmbH:

3-[[3,5-bis(trifluoromethyl)phenyl]amino]-4-[[(8α,9S)-6′-methoxycinchonan-9-yl]amino]-3-Cyclobutene-1,2-dione

Cas No:

1256245-84-7