Catalytic Asymmetric Synthesis of Quaternary Barbituric Acids.
DOI Number:
10.1021/jacs.7b09124
Reaction Category:
RXNO ID:
RXNO_0000009
Educt:
1-Methyl-5-(phenylmethyl)-2-[(phenylmethyl)thio]-4,6(1H,5H)-pyrimidinedione, 1-(3-Methylphenyl)-2-propen-1-one
Product:
(5R)-1-Methyl-5-[3-(3-methylphenyl)-3-oxopropyl]-5-(phenylmethyl)-2-[(phenylmethyl)thio]-4,6(1H,5H)-pyrimidinedione
Catalyst:
3-[[3-[bis[3,5-bis(trifluoromethyl)phenyl]hydroxymethyl]-5-(trifluoromethyl)phenyl]amino]-4-[[(8α,9S)-6′-methoxycinchonan-9-yl]amino]-3-cyclobutene-1,2-dione
Cas No:
2127845-72-9
Associated Product from Buchler GmbH:
Quinine Base
Cas No:
130-95-0