Enantioselective Total Synthesis of (+)-Lucidumone via Organocatalytic Double Michael Addition.
DOI Number:
10.1021/acs.orglett.5c03633
Reaction Category:
MOP ID:
MOP_0000561
Educt:
1-(2,5-dimethoxyphenyl)-3-nitroprop-2-en-1-one, methyl 3-(hydroxymethyl)-2-oxocyclohex-3-ene-1-carboxylate
Product:
methyl 2-(2,5-dimethoxybenzoyl)-5-(hydroxymethyl)-3-nitro-6-oxobicyclo[2.2.2]octane-1-carboxylate
Catalyst:
(8α,9R)-Cinchonan-6′,9-diol-9-benzoate
Cas No:
876269-54-4
Associated Product from Buchler GmbH:
Cupreine Base
Cas No:
524-63-0