Direct Carbon−Carbon Bond Formation via Soft Enolization: A Biomimetic Asymmetric Mannich Reaction of Phenylacetate Thioesters.

DOI Number:

10.1021/ol101152b

Reaction Category:

Educt:

(E)-N-(2-methylbenzylidene)benzenesulfonamide, S-ethyl 2-phenylethanethioate

Product:

S-ethyl (2S,3S)-2-phenyl-3-(phenylsulfonamido)-3-(o-tolyl)propanethioate

Catalyst:

N-[(8α,9S)-10,11-Dihydro-6′-methoxycinchonan-9-yl]-N′-phenylurea

Cas No:

1236212-68-2

Cas No:

522-66-7