Control of Reactions of Pyruvates by Catalysts: Direct Enantioselective Mannich Reactions of Pyruvates Catalyzed by Amine-based Catalyst Systems.
DOI Number:
10.1021/acs.orglett.2c00436
Reaction Category:
RXNO ID:
RXNO_0000032
Educt:
cyclic sulfonylimines, pyruvates
Product:
substituted (S)-3-(2,2-dioxido-3,4-dihydrobenzo[e][1,2,3]oxathiazin-4-yl)-2-oxopropanoates
Catalyst:
2-nitrobenzoic acid, (8α,9S)-6′-Methoxycinchonan-9-amine
Cas No:
168960-95-0
Associated Product from Buchler GmbH:
Quinine Base
Cas No:
130-95-0