Control of Reactions of Pyruvates by Catalysts: Direct Enantioselective Mannich Reactions of Pyruvates Catalyzed by Amine-based Catalyst Systems.

DOI Number:

10.1021/acs.orglett.2c00436

Reaction Category:

Educt:

cyclic sulfonylimines, pyruvates

Product:

substituted (S)-3-(2,2-dioxido-3,4-dihydrobenzo[e][1,2,3]oxathiazin-4-yl)-2-oxopropanoates

Catalyst:

2-nitrobenzoic acid, (8α,9S)-6′-Methoxycinchonan-9-amine

Cas No:

168960-95-0

Cas No:

130-95-0