Asymmetric approach toward chiral cyclohex-2-enones from anisoles via an enantioselective isomerization by a new chiral diamine catalyst.
DOI Number:
10.1021/ja308623n
Reaction Category:
Educt:
5,5-dimethyl-3,4,5,6,7,8-hexahydronaphthalen-2(1H)-one
Product:
(S)-5,5-dimethyl-4,4a,5,6,7,8-hexahydronaphthalen-2(3H)-one
Catalyst:
(R)-2-chloropropanoic acid, N1-[(9R)-6′-methoxycinchonan-9-yl]-4-(trifluoromethyl)-1,2-benzenediamine
Cas No:
1404088-26-1
Associated Product from Buchler GmbH:
Quinidine Base
Cas No:
56-54-2