Silver‐Catalyzed Asymmetric Dearomatization of Electron‐Deficient Heteroarenes via Interrupted Barton–Zard Reaction.

DOI Number:

10.1002/anie.202107767

Reaction Category:

Educt:

1-protected 3-nitro-1H-indole, 2-substituted 2-isocyanoacetates

Product:

substituted 8b-nitro-3,3a,4,8b-tetrahydropyrrolo[3,4-b]indole-3-carboxylate

Catalyst:

2-(diphenylphosphino)-N-[(8α,9S)-6′-methoxycinchonan-9-yl]-benzamide

Cas No:

1630973-03-3

Cas No:

130-95-0