The origin for highly enantioselective induction of 1-naphthol to isatin-derived N-Boc ketimines catalyzed by quinine thiourea catalyst: an experimental and computational study.
DOI Number:
10.1039/c5ra12795e
Reaction Category:
RXNO ID:
RXNO_0000369
Educt:
1-naphthol, N-[1,2-dihydro-2-oxo-1-(phenylmethyl)-3H-indol-3-ylidene]-Carbamic acid-1,1-dimethylethyl ester
Product:
tert-butyl (R)-(1-benzyl-3-(1-hydroxynaphthalen-2-yl)-2-oxoindolin-3-yl)carbamate
Catalyst:
N-[3,5-Bis(trifluoromethyl)phenyl]-N′- [(8α,9S)-6′-methoxycinchonan-9-yl]thiourea
Cas No:
852913-16-7
Associated Product from Buchler GmbH:
Quinine Base
Cas No:
130-95-0